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Photochromie In ihrer Zuschrift auf S. 440 ff. berichten H.‐C. Zhou et al. über zwei photochrome Metall‐organische Gerüste. Mit einem dieser Gerüste gelingt die reversible kontrollierte Erzeugung von Singulett‐Sauerstoff.
The controlled generation of singlet oxygen is of great interest owing to its potential applications including industrial wastewater treatment, photochemistry, and photodynamic therapy. Two photochromic metal–organic frameworks, PC‐PCN and SO‐PCN, have been developed. A photochromic reaction has been successfully realized in PC‐PCN while maintaining its single crystallinity. In particular, as a solid‐state...
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