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Non‐benzenoid polycyclic aromatic hydrocarbons (PAHs) have received a lot of attention because of their unique optical, electronic, and magnetic properties, but their synthesis remains challenging. Herein, we report a non‐benzenoid isomer of peri‐tetracene, diazulenorubicene (DAR), with two sets of 5/7/5 membered rings synthesized by a (3+2) annulation reaction. Compared with the precursor containing...
Organic Semiconductors. In their Research Article (e202304632), Xi‐Sha Zhang, Deqing Zhang et al. report a (3+2) annulation reaction to synthesize diazulenorubicenes showing semiconducting properties.
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