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In article number 2001989, Xianhong Rui, Yan Yu, and co‐workers develop a Li salt, lithium bisoxalatodifluorophosphate (LiDFBOP), to modify the solid‐electrolyte interphase (SEI) in fluoroethylene carbonate (FEC)–based electrolyte for lithium metal batteries. Benefiting from the synergetic effect of the LiDFBOP and FEC, a fluorinated SEI rich in LiF and LixPOyFz species is achieved, demonstrating...
Fluorinated solid‐electrolyte interphase (SEI) derived from fluoroethylene carbonate (FEC) is particularly favored for dendrite suppression in lithium metal batteries because of the high Young's modulus (≈64.9 Gpa) and low electronic conductivity (10−31 S cm−1) of LiF. However, the transportation ability of Li+ in this fluorinated SEI under high current densities is limited by the low ionic conductivity...
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