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Icosahedral, octahedral, and cubic Pd@Pt core–shell nanocrystals with two atomic Pt layers are epitaxially generated under thermodynamic control. Such icosahedra exhibit remarkably enhanced catalytic properties for oxygen reduction reaction compared to the octahedra and cubes as well as commercial Pt/C, which can be attributed to ligand and geometry effects, especially twin‐induced strain effect that...
In article number 1603423, He Tian, Jianbo Wu, Hui Zhang, and co‐workers develop a thermodynamically controlled method for the epitaxial growth of atomically layered Pt shells on icosahedral, octahedral, and cubic Pd seeds, with Pd‐Pt core‐shell icosahedra being the best electrocatalysts for oxygen reduction reaction. The cover image shows that most of Pt shells in the icosahedra are dominated by...
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