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The hydrothermal method was first employed to synthesize the precursor powders for fabricating the Li4SiO4 ceramic pebbles. Compared with the sol–gel method, the precursor powders synthesized by hydrothermal process are much more homogeneous and have smaller grain size, which is helpful to obtain Li4SiO4 pebbles with small grain size. Li4SiO4 pebbles were obtained by sintering the green bodies of...
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