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Two new MnII/III redox pairs, [Mn(qsal‐Cl)2]0/+10/+ and [Mn(qsal‐Br)2]0/+20/+ have been synthesized employing the tridentate Schiff base ligands, 5‐X–N‐(8‐quinolyl)salicylaldimine (Hqsal‐X, X = Cl and Br). The neutral MnII complexes 1 and 2 were prepared from MnCl2 and Hqsal‐Cl and Hqsal‐Br while oxidation of 1 or 2 with AgOTf yields the cationic MnIII complexes, [Mn(qsal‐Cl)2]OTf, 1+, and [Mn(qsal‐Br)...
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