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A sustainable and cost‐effective protocol for direct aminomethylation of imidazo‐fused heterocycles by decarboxylative coupling reaction of N‐phenylglycines with imidazo‐fused heterocycles in the presence of CsPbBr3 under the irradiation of visible light has been developed. This is the first example of CsPbBr3‐catalyzed aminomethylation of imidazo‐fused heterocycles. The eminent advantage of this...
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