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The cocatalytic effect of SnO 2 on the iron(III) porphyrins-catalyzed aerobic Baeyer–Villiger oxidation of cyclohexanone in the presence of benzaldehyde as reductant was investigated, the conversion of cyclohexanone was remarkablely enhanced, reaching up to 96%. The major role of SnO 2 was to active cyclohexanone molecules, which was confirmed by in situ Raman spectroscopy. A plausible...
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