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Two coordination polymers, namely {[Co2L(dpe)2]·0.42H2O} (1), and {[Zn4L2(dpe)4]·4H2O} (2), were solvothermally prepared from a flexible tetrapodal ligand tetrakis[(3-carboxyphenyl)oxamethyl]methane acid (H4L) and a secondary bidentate linker (E)-1,2-di(pyridin-4-yl)ethane (dpe). Single-crystal X-ray diffraction analysis revealed that these compounds possess similar three-dimensional structures, in...
Using an octadentate ligand, namely tetrakis[(3,5-dicarboxyphenoxy)methyl] methane (H8L), four coordination polymers, [Ni3L(OH)2(H2O)2][NH2(CH3)2]4·5H2O (1), [Co4L(H2O)4]·9H2O (2), [Zn4L(H2O)4]·DMF·11H2O (3) and [Li4(H4L)(H2O)4] (4) (DMF = N,N-dimethylformamide), have been solvothermally synthesized and structurally characterized by X-ray crystallography. Complex 1 is an anionic three-dimensional...
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