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A novel coordination polymer [Zn(HL)(bpy)(H2O)] (1) has been prepared by utilizing π-conjugated aromatic ligand 5-((4-carboxyphenoxy)methyl)benzene-1,3-dioic acid (H3L) and rigid ligand 4,4′-bipyridine (bpy) under the hydrothermal condition. Compound 1 has been characterized by single crystal X-ray diffraction, power X-ray diffraction, elemental analysis, and thermogravimetric analysis. The structure...
Six organophosphine/phosphite stabilized silver(I) methanesulfonates of type [L n AgO 3 SCH 3 ] (L=Ph 3 P, n=1, 2a; n=2, 2b; n=3, 2c; L=(EtO) 3 P; n=1, 2d; n=2, 2e; n=3, 2f) were synthesized by the reaction of silver methanesulfonates with triphenylphosphine or triethylphosphite in dichloromethane under nitrogen atmosphere. These complexes were obtained in high...
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