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An oxygen concentration dependent metal–nonmetal (MN) transition was observed for Rb0.23WOy with 2.80 < y < 3.08. As 2.80 < y < 3.0, the room temperature resistivity (ρRT) of the Rb0.23WOy is about 5 × 10−4Ω cm. While in the case of y > 3.04, the ρRT of the Rb0.23WOy exhibits a four orders of magnitude increase with a value of 5 Ω cm. Correspondingly, the lattice constant along...
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