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An alumina supported molybdenum nitride catalyst (Mo2N/Al2O3) is examined for the ethanolysis of Kraft lignin in supercritical ethanol in a batch reactor with an initial nitrogen pressure of 0MPa (gauge). No char or tar is formed in this process. The Mo loading as well as the nitriding temperature in the catalyst preparation process has a great influence on the activity. The best performance is obtained...
We report the complete ethanolysis of Kraft lignin over an α‐MoC1−x/AC catalyst in pure ethanol at 280 °C to give high‐value chemicals of low molecular weight with a maximum overall yield of the 25 most abundant liquid products (LP25) of 1.64 g per gram of lignin. The LP25 products consisted of C6–C10 esters, alcohols, arenes, phenols, and benzyl alcohols with an overall heating value of 36.5 MJ kg...
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