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One unusual aromatic monacolin analog, aromonacolin A (1), was isolated from the ethanolic extract of Monascus purpureus‐fermented rice. Its structure was elucidated by extensive spectroscopic (HRESIMS, 1H NMR, 13C NMR, HSQC, HMBC, and NOESY) and chemical methods. The absolute configuration of the C‐6 secondary alcohol was deduced via the circular dichroism data of the in situ formed [Rh2(OCOCF3)4...
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