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Three new alkaloids, brocaeloids A–C (1–3), containing C‐2 reversed prenylation, were isolated from cultures of Penicillium brocae MA‐192, an endophytic fungus obtained from the fresh leaves of the marine mangrove plant Avicennia marina. Their structures were determined on the basis of 1D and 2D NMR spectroscopy as well as by high‐resolution mass spectrometry. The absolute configuration of brocaeloid...
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