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The development of van der Waals heterostructures in 2D materials systems has attracted considerable interests for exploring new insights of (opto‐) electrical characteristics, device physics, and novel functional applications. Utilizing organic molecular material with strong electron withdrawing ability, charge transfer van der Waals interfaces are formed between 2,3,5,6‐tetrafluoro‐7,7,8,8‐tetracyanoquinodimethane...
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