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A novel self‐supporting palladium catalyst based on a polymer containing bulky N‐heterocyclic carbene [P(b‐NHC‐Pd)] is prepared successfully by a simple method, and its palladium content reaches 1.35 mmol g−1. Due to the bulky structure of NHC‐PdCl2‐3‐chloropyridine and high content of palladium active sites, this catalyst exhibits excellent catalytic activity for a wide variety of different substrates...
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