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A family of phenoxy-imine-ether ligated Ti complexes for selective ethylene trimerization have been developed from highly active bis(phenoxy-imine) early transition metal ethylene polymerization catalysts. The Ti complexes, after activation with methylaluminoxane (MAO), selectively trimerized ethylene to produce 1-hexene with exceptionally high productivity under mild conditions (e.g., 1-hexene selectivity...
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