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We have prepared the tetranuclear palladium complex [Pd 4 (μ-dppm) 4 (μ 4 -S)] (1) capped by a μ 4 -bonded sulfide and crystallographically characterized it. Four Pd atoms are bridged by four dppm ligands to form the rectangular Pd 4 core, which are capped by the μ 4 -bonded sulfide from the side above the Pd 4 plane. It was suggested that...
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