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The uncontrollable dendrite growth and unstable solid electrolyte interphase have long plagued the practical application of Li metal batteries. Herein, a dual‐layered artificial interphase LiF/LiBO–Ag is demonstrated that is simultaneously reconfigured via an electrochemical process to stabilize the lithium anode. This dual‐layered interphase consists of a heterogeneous LiF/LiBO glassy top layer with...
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