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Electronic band structures of two novel semiconducting nitrides of the group‐IV elements of Th3P4‐type crystal structure, c‐M3N4, where MZr or Hf, is investigated using an element specific soft X‐ray spectroscopy for the first time. From the pairs of N 1s X‐ray absorption and N 2p → 1s resonant X‐ray emission spectra partial densities of states (PDOS) of nitrogen, predicted to be strongly hybridized...
The thermal behavior of zinc carbodiimide Zn(NCN) was examined in the temperature range between 200 and 1100 °C in Ar atmosphere. The material starts to partially decompose at about 800 °C. Heat treatment at temperatures beyond 800 °C results in the formation of the byproducts nitrogen-containing bamboo-like multiwall carbon-nanotubes of 20–50 nm in diameter due to a partial decomposition of Zn(NCN)...
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