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The synthesis, single crystal structure, luminescent and electrochemistry properties of a Cu(I) compound based on in situ formation ligand, namely [1,2,3]triazolo[1,5-α]quinoline(L1), are reported. Complex [Cu4IBr4(L1)4] (1) is the first example of Cu(I) species with [1,2,3]triazole-ligand and provides the direct evidence for Cu(II) role to the ring-closure of hydrazone.
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