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An equation of state (EOS) using an improved expression of the coordination number model for square well (SW) fluids with variable well width was applied for vapor–liquid equilibrium (VLE) calculations of non-polar fluid mixtures and polymer solution. This modified coordination number model was compared with other equations in literature. Better agreement with molecular simulation data for fluid mixtures...
The generalized-Flory dimer (GFD) equation of state (EOS) is combined with the UNIFAC-FV group contribution G E model to yield predictive vapor-liquid equilibrium calculations of polymer solutions. The equilibrium pressures, solvent solubility and activity of various binary systems are calculated. The GFD/G E method predicts good results in comparison to those from other optimally...
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