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The reaction of 1H‐tetrazole‐1‐acetic acid (Htza) and perchloric acid with cuprous chloride with slow evaporation at room temperature gave a novel 3D porous CuII coordination polymer, [Cu2(tza)4]·ClO4·4H2O (1), (tza = tetrazole‐1‐acetate). The structure exhibits an unusual 3D microporous coordination framework built up by four coordinated CuII nodes and bidentate bridging tza ligands with lvt‐type...
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