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Palladium(II) complexes with an auxiliary bidentate ligand featuring one C–Pd bond and a Pd–N-donor bond (palladacycles) have been shown to afford improved yields of homoallylic amines from a three-component coupling of boronic acids, allenes and imines in comparison to the yields of homoallylic amines achieved with the originally reported catalyst (Pd(OAc) 2 /P(t-Bu) 3 ), thus extending...
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