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Millimeter-wave absorption spectroscopy combined with a pulsed jet expansion technique was applied to measure the internal rotation j=2–1 hot band of the Ar–HCN complex in the frequency region of 147–287GHz. In total 153 rovibrational lines, split into hyperfine components due to the nitrogen nucleus, were assigned to the Σ 2 –Σ 1 , Σ 2 –Π 1 , Π 2 –Σ 1 ...
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