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Two ternary complexes [Cu(ala-gly)(isocyt)(H 2 O)].H 2 O (1) and [Cu(L-tyr-gly) (isocyt)].3H 2 O (2) have been prepared and characterised by X-ray diffraction, optical, ESR and IR spectral data. Both compounds exist as slightly distorted square-planar complexes, with the four co-ordination sites occupied by the tridentate peptidic dianion [oxygen carboxylic O(7), nitrogen amidic...
The lilac complex [Ni(en) 2 (isocyt) 2 ][B(C 6 H 5 ) 4 ] 2 (en=ethylenediamine; isocyt=isocytosine) has been prepared by reaction of [Ni(en) 2 Cl] 2 Cl 2 and the pyrimidine base in ethanol–water medium. The complex crystallizes in the triclinic space group P-1 with a=9.488(6), b=11.020(5), c=13.986(6) Å, α=84.09(4), β=85.33(5),...
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