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Novel dual potentiometric microsensor probe has been developed for the simultaneous detection of Zn2+ concentration and pH distributions in the Scanning Electrochemical Microscopy investigation of corroding galvanized steel. The individual sensors show nearly theoretical behavior over a wide concentration range. The applicability of this probe is first demonstrated on a Fe-Zn galvanic couple, as it...
Application of scanning vibrating electrode technique (SVET) for corrosion studies of organic coatings on reactive metals is presented. SVET was used to monitor the electrochemical processes at painted steel immersed in either 10mM Na 2 SO 4 or 10mM NaCl aqueous solutions. The coated samples were investigated after a scratch was operated through the polymer matrix down to the metal–substrate...
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