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The dynamics of the enthalpy and volume changes related to the photo-dissociation of oxygen from human and bovine oxyhemoglobin are investigated by nanosecond time-resolved photoacoustic calorimetry (PAC). The values of enthalpy and volume change associated with the above process are ΔH=37.8+/-3kcal/mol, ΔV=5.0+/-1ml/mol for human HbO 2 ; and ΔH=35.7+/-3.5kcal/mol, ΔV=4.8+/-1ml/mol for bovine...
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