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So far, only five primary elements (C, H, O, N and B) and two types of spatial configuration (C2–C4, C6 and Td) are reported to build the monomers for synthesis of covalent organic frameworks (COFs), which have partially limited the route selection for accessing COFs with new topological structure and novel properties. Here, we reported the design and synthesis of a new “stereoscopic” 2D super-microporous...
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