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A series of benzene-co-fluorene copolymers were synthesized via solid-state oxidative coupling polymerization using FeCl3 as the oxidation catalyst. The structural characterization results confirm that the products are random copolymers composed of 1,4-linked phenylene units and 2,7-linked fluorene units. All the copolymers exhibited good thermal stability. The DSC and XRD results showed that the...
Poly(alkoxynaphthalene)s were synthesized by grinding 2-alkoxynaphthalenes with FeCl3 as the oxidant at room temperature via solid-state oxidative coupling polymerization. Based on the structural characterization and analysis, the condensed structure of 1,4-linked polynaphthalenes is the dominant structure of the polymer, accompanied with the formation of intramolecular coupling. The polymers not...
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