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The characteristics of negative ion states formed by temporary electron attachment to adsorbed molecules depend on the environment of the molecule. Adsorption site effects on the energy positions and widths of the N2-2Πg resonance are theoretically investigated for a nitrogen molecule adsorbed on an Ar monolayer covering a Cu metal substrate. The molecule is shown to preferentially adsorb above the...
Inelastic electron scattering data are used to study the geometry of molecular adsorbates on metal surfaces. The analysis of the vibrational excitation of N 2 molecules physisorbed at 15K on Ag(110) by electron impact provides information on the orientational ordering of the molecules on the surface. The incident electron energy (19eV) is in the range where vibrational excitation is dominated...
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