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Composition-induced structural phase changes across the high temperature, fast oxide ion conducting (Ba 1−x La x ) 2 In 2 O 5+x , 0⩽x⩽0.6, system have been carefully analysed using hard mode infrared (IR) powder absorption spectroscopy, X-ray powder diffraction and electron diffraction. An orthorhombic brownmillerite to three-dimensionally disordered...
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