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Hydrogels crosslinked by dynamic covalent bonds can effectively mimic the viscoelastic properties of native extracellular matrix and have been widely explored for 3D cell culture. Disulfide is one of the most common dynamic bonds in biological systems whose formation and cleavage are catalyzed by a set of dedicated enzymes. However, in vitro formation of disulfide bonds is a slow process and requires...
Polymer‐supramolecular double‐network hydrogels (PS‐DN hydrogels) often show much improved recovery rates than conventional double‐network hydrogels because of the fast self‐assembling properties, making them attractive candidates for tissue engineering and flexible electronics. However, as the supramolecular network is dynamic and susceptible to break under low strains, the overall mechanical properties...
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