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In this micro-review, the concepts that have led to ligand activation and redox robustness with organoiron complexes in the authors’ laboratory are developed. It is shown how these activation modes have led to the construction of redox-active metallodendrimers including various types of mixed-valent complexes with application to redox recognition, sensing and controlled nanoparticle synthesis.
This article is a mini-review mostly based on the work of the authors’ laboratory on the redox chemistry of metallodendrimers and gold nanoparticles, with emphasis on “click” chemistry. Late transition-metal sandwich complexes possess a rather unique ability to withstand two or three oxidation states without breakdown, especially with permethylated π-cyclopentadienyl or arene ligands. When they are...
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