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The one-pot three-step continuous enzymatic synthesis of 5-fluoro-5-deoxy-d-ribose (5-FDR) from ATP and l-methionine using S-adenosyl-l-methionine synthase (MetK), fluorinase and methylthioadenosine nucleosidase (MtnN) in the presence of fluoride ion, was described. Especially, for the purpose of the sustainable development of fluorine chemistry, the reuse of fluoride ion generated from BF 4 ...
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