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Advanced crosslinked polymeric materials based on poly(ionic liquid)s, also named supported ionic liquid-like phases (SILLPs) combine some unique characteristics of ionic liquids with the general property profile of macromolecular architectures, and present huge potential in energy-/environment-/catalysis-oriented applications, in the development of “smart” dispersants and stabilizers, etc. One of...
New polymeric materials containing functional sites analogous to ionic liquids have been synthesized. Those materials are a supported reservoir for the active Pd species. Their catalytic activity has been evaluated for the Heck reaction proving an excellent performance in terms of both activity and recyclability. Although soluble Pd species seem to participate in the catalytic cycle, as for many other...
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