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Iron(III)‐centered star polymers of poly(ε‐caprolactone) (PCL) and copolymers with polylactide have been synthesized by a divergent ring‐opening polymerization initiated from an alcohol‐functionalized dibenzoylmethane (dbm) complex. This strategy provides a route to well‐defined polyester products with relatively high molecular weights and low PDIs. These reactions require no added catalyst. The resulting...
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