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Fe(II)-Al(III)-LDH (layered double hydroxide) phases have been shown to form from reactions of aqueous Fe(II) with Fe-free Al-bearing minerals (phyllosilicate/clays and Al-oxides). To our knowledge, however, the effect of small amounts of structural Fe(III) in natural clays on such reactions were not studied. In this study to understand the role of structural Fe(III) in clay, laboratory batch studies...
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