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Three polyethylene containing different non-planar aliphatic ring ether units (1,4-cyclohexylenedioxy, 4,4′-bicyclohexylenedioxy and 4,4′-isopropylidenedicyclohexylenedioxy) were synthesized via acyclic diene metathesis polymerization (ADMET) and subsequent hydrogenation. They were compared with their counterpart polymers containing aromatic ring defects in aspects of chain structural, thermal properties...
1,3‐Dithiane and its derivatives are widely used as powerful acyl anion equivalent to a range of useful transformations that are needed in the synthesis of natural products. In this work, a series of polyolefins containing pendant dithiane groups have been designed and synthesized via acyclic diene metathesis polymerization (ADMET) polymerization and subsequent hydrogenation. The structures of these...
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