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Semicrystalline polymers have to be described by a three phase model consisting of a mobile amorphous (MAF), a crystalline (CF), and a rigid amorphous fraction (RAF). For nanocomposites based on a semicrystalline polymer the RAF is due to both the crystallites (RAFcrystal) and the filler (RAFfiller). Polymer nanocomposite based on poly(l-lactide) and MgAl layered double hydroxide nanofiller were prepared...
A novel dual-responsive core-shell type hybrid inclusion complex composed of an azobenzene-terminated copolymer PNIPAM-b-PAA and β-cyclodextrin-modified silver/polydiacetylene (β-CD@Ag/PDA) nanocrystals had been fabricated based on the host-guest interaction between azobenzene unit in the block copolymer and β-CD cavities on the surface of the hybrid nanocrystals. While the hybrid nanocrystals provide...
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