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The origin of dolomite has been an issue for hundreds of years, and its kinetic inhibition is a critical aspect of this issue. Dissolved sulfate is regarded as an inhibitor for dolomite formation because it can bind Mg2+ to form tight ion pairs and thus prevent the incorporation of Mg2+ into dolomite. Using Raman spectroscopy, we investigated the Mg2+–SO42− association in vapor-saturated aqueous MgSO...
The phase behaviors of aqueous UO2SO4 solutions were investigated in situ with a microscope and a Raman spectrometer at temperatures from 25 to 420°C. Results show that aqueous UO2SO4 solution separated into UO2SO4-rich (Urich) and UO2SO4-poor (Upoor) liquid phases coexisted with a vapor phase at ≥285.8±0.5°C. Both visual and Raman spectroscopic investigations suggest that a reversible strong UO22+...
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