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Lithium‐ion batteries (LIBs) using tellurium (Te) as electrode material are appealing because of their high capacities, conductivities, and lithium‐ion diffusivity relative to those of silicon. However, crystalline Te electrode suffers from mechanical instability and poor cyclability during Li+ insertion and extraction. Moreover, the reaction mechanisms governing Te electrode during the electrochemical...
Lithium‐Ion Storage
In article number 2310170, Ran Cai, Ruiwen Shao, Lixin Dong, and co‐workers present the results of comparative operando experiments on the crystalline and amorphous Te phases when the amorphous Te phase is deliberately conducted. The lithiation of the crystalline Te phase results in grains with concomitant pulverization. However, the amorphous Te specimens show promising lithiation/delithiation...
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