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A new complex [Cu 2 Zn(O 2 CMe) 6 (NH 3 ) 2 ] n was isolated as an unexpected product in an open-air synthesis of a mixed-metal compound using zero-valent copper, zinc oxide and ammonium acetate in the presence of 2-diethylaminoethanol in acetonitrile solution. Its structure consists of Cu 2 (O 2 CMe) 4 units situated on crystallographic...
The novel hybrid composites [Cu(Hdea)(H 2 dea)] 2 [CdX 4 ], X=Br (1), I (2) have been prepared in reactions of zero-valent copper with cadmium halide in air-exposed solution containing the corresponding ammonium salt and diethanolamine (H 2 dea). X-ray crystallographic analysis reveals ionic solids of non-symmetric H-bonded dimeric [Cu(Hdea)(H2dea)]22+ cations and perhalocadmate...
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