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A new complex [Mn2(C12H12N2)3(C14H8O4)2 (C2H5OH)2]n (where C14H8O4 is 2,2′-bi-phenyldicarboxy- late, bpda; C12H12N2 is benzidine), has been solvothermally synthesized at 443 K and characterized by the elemental analyses, IR, and the single crystal X-ray diffraction analysis. The title complex crystallizes in the triclinic system, space group P-1, with a=9.472 (4) Å, b=12.638(5) Å, c=13.434(5) Å,...
Two novel supramolecular complexes [Ni(cyclen)(H2O)2](tpa)(1) and [Cu(cyclen)H2O](tpa)⋅3H2O (2) were synthesized and their structures were characterized with elemental analysis, IR spectrum, TGA and X-ray diffractometer, indicating that the complexes 1 and 2 consist of one-dimensional chain and two-dimensional net-work structures formed by intermolecular hydrogen-bonding interaction, respectively...
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