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The electrodeposition of Zn–Mn alloys was performed using a chloride-based acidic bath containing ammonium thiocyanate (NH 4 SCN) as an additive. An electrochemical study using cyclic voltammetry (CV), performed for each of the metal ions (Zn(II) and Mn(II)), showed that neither metal ion forms complexes with NH 3 , and that Mn(II) but not Zn(II) forms complexes with SCN − ...
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