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Die Reaktivität des binären Anions (TlBi3)2− gegenüber Gruppe‐12‐Metallverbindungen MPh2 (M=Zn, Cd, Hg) wurde studiert, um einen Zugang zu Koordinationsverbindungen polyzyklischer Moleküle wie Bi73− oder Bi113− zu erhalten. Die Koordinationschemie dieser Polybismutid‐Käfige war bislang unklar, während sie für die leichteren Anionen der Gruppe 15, Pn73− (Pn=P, As, Sb), seit vielen Jahren bekannt ist...
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