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A detailed structural study of selected compositions in the Bi 3 Nb 1−x Zr x O 7−x/2 system using combined X-ray and neutron powder diffraction techniques is presented. Two distinct composition regions are evident. A limited pseudo-cubic solid solution range is observed up to ca. x=0.4 and details of the defect structure are presented and compared with conductivity...
Structural and electrical investigations in the Bi 3 Nb 1−x Zr x O 7−x/2 system have been carried out using X-ray powder diffraction and AC impedance spectroscopy. Several different fluorite phases are observed in the system. At low substitutions (0.0≤x≤0.40), a fluorite δ-Bi 2 O 3 -type phase is observed with a fully reproducible linear Arrhenius plot...
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