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Applying in situ surface X-ray diffraction (SXRD) together with on-line mass spectrometry during the CO oxidation over Ru(0001) allows a direct comparison of the reactivity of the non-oxidic state with that of the RuO 2 (110) covered surface. This comparison reveals that the RuO 2 (110) surface is a catalytically active phase at least as active as the non-oxidic phase. At high CO and...
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