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ZrO2 is an effective nucleation agent for low‐expansion lithium–aluminum silicate (LAS) glass–ceramic (GC) with high Al2O3 content. However, the effect of ZrO2 is still not fully understood in LAS glasses with low contents of Al2O3 and P2O5. In this work, the effect of ZrO2 on the phase separation and crystallization of Li2O–Al2O3–SiO2–P2O5 glasses were investigated. The results revealed that ZrO2...
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