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A fluorinated electrolyte mixture, containing 1 M LiPF6/fluoroethylene carbonate:bis (2,2,2-trifluoroethyl) carbonate (1:1 w:w) with prop-1-ene-1,3-sultone as an electrolyte additive exhibited promising cycling and storage performance in Li(Ni0.4Mn0.4Co0.2)O2/graphite pouch type Li-ion cells tested to 4.5 V. The prop-1-ene-1,3-sultone additive was added to help control gas evolution in the fluorinated...
The effectiveness of some selected electrolyte additive blends were systematically studied in Li[Ni0.4Mn0.4Co0.2]O2/graphite and 3 wt% LaPO4-coated Li[Ni0.4Mn0.4Co0.2]O2/graphite pouch cells using ex-situ gas measurements, ultra high precision coulometry, automated storage experiments, long-term cycling and electrochemical impedance spectroscopy. For cells tested to an upper cutoff potential of 4...
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